All diesel sold in the UK already has 5% Biodiesel mixed in with it. In theory, you should be able to run your Golf 150 on pure Biodiesel, but the source of your fuel is of utmost importance. This is tha main reason that manufacturers are holding back from full certification for all their diesel engines, because they can't guarantee the source of the fuel to be pure enough. If they stated that all diesels could run on 100% Biodiesel, numpties would immediately assume that sticking 50ltrs of Tesco finest cooking oil in the tank was okay. Biodiesel is one thing, cooking oil with conversion kits, mixed with white spirit, waste oil from the local chippie etc. is a completely different issue and not to be confused with Biodiesel.
So if your source of Biodiesel is from a refinery where the supply is certified to EN14214 you should be fine with it. If it's home brewed, or from a bloke you met down the pub, then probably not.
Also, more frequent oil changes are a good idea initially to make sure that you're not contaminating the sump oil with vegetable matter. There's some pics doing the rounds on the net of someone who used freely available Biodiesel or veg oil from some unknown source and the sump is full of solid black sludge.
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